基于有限元模拟的褐煤自燃程序升温特性研究

Programmed temperature rise characteristics of lignite spontaneous combustion based on finite element simulation

  • 摘要: 为了更好地理解褐煤氧化反应过程,预测并控制褐煤自燃的产生以及发展,采用程序升温实验研究了褐煤氧化反应特性。分析褐煤氧化反应过程的关键参数,并基于有限元模拟建立褐煤-氧化学反应动力学模型,研究了褐煤氧化反应过程中温度和气体的演变规律。此外,通过改变环境中氧气的体积分数和升温速率,研究了温度以及出口氧气浓度的变化规律。结果表明,在褐煤-氧反应过程中,由于其发展历程和环境约束条件的动态变化,温度和氧气浓度对褐煤氧化反应速率的主导作用也随之改变。耗氧量随着褐煤样粒径的减小或温度的增加而增加;通过改变氧气体积分数与程序升温速率,发现增加氧气体积分数和提高升温速率都可以促进褐煤-氧反应进程,并减少外界升温引领褐煤氧升温的滞后效应。控制褐煤与氧气发生反应的储温条件,有利于预防早期的褐煤氧化反应;改变供氧条件,则能够控制后期褐煤的自燃发展。

     

    Abstract: In order to better understand the process of lignite oxidation reaction, predict and control the generation and development of lignite spontaneous combustion, the characteristics of coal oxidation reaction were studied based on experimental conditions.The key parameters of the lignite oxidation reaction process were analyzed, and a kinetic model of the lignite-oxidation chemical reaction was established based on the finite element simulation.The evolution laws of temperature and gas during the lignite oxidation reaction process were studied.By altering the volume fraction of oxygen in the environment and the heating rate, the variation laws of temperature and the oxygen concentration at the outlet were studied.The results show that during the lignite-oxygen reaction process, due to the dynamic changes in its development history and environmental constraints, the dominant roles of temperature and oxygen concentration in the rate of lignite oxidation reaction also change accordingly.The oxygen consumption increases with the decrease in the particle size of the lignite sample and the increase in temperature.By changing the volume fraction of oxygen and the programmed temperature rise rate, it was found that both increasing the volume fraction of oxygen and enhancing the temperature rise rate could promote the lignite-oxygen reaction process and reduce the lag effect of external temperature rise leading to the temperature rise of lignite and oxygen.Controlling the storage temperature conditions for the reaction between lignite and oxygen is conducive to preventing the early coal oxidation reaction, while changing the oxygen supply conditions can control the development of lignite spontaneous combustion in the later stage.

     

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